Which of the following has highly acidic hydrogen?

Given below are two statements:
Statement $I:$ Ethyl pent$-4-$yn$-$oate on reaction with $CH_{3}MgBr$ gives a $3^{\circ}$ alcohol.
Statement $II:$ In this reaction,one mole of ethyl pent$-4-$yn$-$oate utilizes two moles of $CH_{3}MgBr$.
In the light of the above statements,choose the most appropriate answer from the options given below:

Which of the following carboxylic acids could be resolved by reaction with an enantiomerically pure chiral amine?

Match the following.

List-$I$ (Substance)	List-$II$ (Use)
$(A)$ Methanoic acid	$(i)$ Textile
$(B)$ Ethanoic acid	$(iv)$ Vinegar
$(C)$ Hexanedioic acid	$(ii)$ Polymer
$(D)$ Sodium benzoate	$(iii)$ Food preservative

The major product in the following reaction is

Find the missing information from the following reactions:
$(i)$ $CH_3COOH \rightarrow[\Delta]{H_2SO_4/P_2O_5} ?$
$(ii)$ $? + CH_3OH \rightleftharpoons[H^{+}]{} CH_3COOCH_3 + H_2O$
$(iii)$ $3 CH_3COOH + PCl_3 \rightarrow 3 CH_3COCl + ?$
$(iv)$ $CH_3COOH + PCl_5 \rightarrow CH_3COCl + ? + HCl$
$(v)$ $C_6H_5COONa \rightarrow{?} C_6H_6$
$(vi)$ $CH_3CH_2COOH \rightarrow{\text{excess } Br_2 + \text{Red } P} ? + ?$
$(vii)$ $CH_3CH_2COOH \rightarrow{?} CH_3CH_2CH_2OH$
$(viii)$ $C_6H_5COOH \rightarrow{\text{anhydrous } AlCl_3, CH_3Cl \text{ or } CH_3COCl} ?$